Polymerizations of propylene oxide (PO) have been carried out by using double metal cyanide (DMC) catalyst prepared by reacting ZnCl 2 and K 3 [Co(CN) 6 ] in the presence of tert-butyl alcohol as a complexing agents. The DMC catalyst of the molecular formula, Zn 2.3 Cl 1.0 [Co(CN) 6 ] 1.0 Á2.0 t BuO
Activity and regioselectivity in the ring-opening reaction of methyloxirane at metal–metal oxide interfaces
✍ Scribed by István Pálinkó
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 63 KB
- Volume
- 140
- Category
- Article
- ISSN
- 1381-1169
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Previously we described the efficient oxidation of l-methoxycyclopropanol 1 with Cu\*+ Ions to methyl acrylate 2 and dimethyl adipate 3 via the methyl P-propionate radical 2. It was proved by labelling experiments 131 that the \*