Activity and Osmotic Coefficients from the Emf of Liquid Membrane Cells. VIII. K.3[Co(CN)6], Mg3[Co(CN)6]2, and Ca3[Co(CN)6]2
β Scribed by Francesco Malatesta; Franco Bruni; Nicolangelo Fanelli; Sara Trombella; Roberto Zamboni
- Book ID
- 110220805
- Publisher
- Springer US
- Year
- 2000
- Tongue
- English
- Weight
- 153 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0095-9782
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π SIMILAR VOLUMES
Tetrapropylammonium and -phosphonium ions, nPr 4 E Ψ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M β«Ψβ¬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]
## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4β^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3β^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__