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Activity and Osmotic Coefficients from the Emf of Liquid Membrane Cells. VIII. K.3[Co(CN)6], Mg3[Co(CN)6]2, and Ca3[Co(CN)6]2

✍ Scribed by Francesco Malatesta; Franco Bruni; Nicolangelo Fanelli; Sara Trombella; Roberto Zamboni


Book ID
110220805
Publisher
Springer US
Year
2000
Tongue
English
Weight
153 KB
Volume
29
Category
Article
ISSN
0095-9782

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4βˆ’^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3βˆ’^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__