## Abstract Sulfonation of norbornene 1 with the SO~3~βdioxane complex affords the Ξ²βsultone 2, which rearranges at room temperature to the Ξ³βsultone 3. Reaction of 1 with 2 equiv of SO~3~βnitromethane yields the carbyl sulfate 4. Carbocations are __not__ involved in the formation of either the Ξ²βs
β¦ LIBER β¦
Active sulfuration of norbornenes
β Scribed by Shields, Theodore C.; Kurtz, A. N.
- Book ID
- 121368571
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 276 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Photochemical reductions of norbornenes
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We would like to report aoam preliminary remltr involving photochemically-induced reduction of several norbornenes (I) to norbornanes (II) (1). Irradiation (2) of various derivatives of I ( X=H, Y=CN; X=CN, Y=E; X=Y=H, X,Y=H,OH; X,Y=H,CO&&) in dilute ( 0.