Active Site Ring-Opening of a Thiirane Moiety and Picomolar Inhibition of Gelatinases
β Scribed by Christopher Forbes; Qicun Shi; Jed F. Fisher; Mijoon Lee; Dusan Hesek; Leticia I. Llarrull; Marta Toth; Michael Gossing; Rafael Fridman; Shahriar Mobashery
- Book ID
- 111368756
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 349 KB
- Volume
- 74
- Category
- Article
- ISSN
- 1747-0277
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A germyl-bridged lanthanocene chloride, Me 2 Ge( t Bu-C 5 H 3 ) 2 LnCl (Ln ΒΌ Nd; (Cat-Nd), was prepared and successfully used as single catalyst to initiate the ringopening polymerization of e-caprolactone (e-CL) for the first time. Under mild conditions (60 C,[e-CL]/[Ln] ΒΌ 200, 4 h), Cat-Nd efficie
Radical polyadditions of vinylcyclopropane having spiroacetal moiety, 1, 10divinyl-4,8,12,15-tetraoxatrispiro[2.2.2.2.2.2]pentadecane ( 1), and various dithiols were examined. 1 was prepared by the reaction of 1,1-dichloro-2-vinylcyclopropane and pentaerythritol, and radical polyadditions of 1 and d