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Activation parameters for the reaction of phenylchloro carbene with pyridine, tri-n-butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins

✍ Scribed by James E. Jackson; N. Soundararajan; Matthew S. Platz; Michael P. Doyle; Michael T.H. Liu


Book ID
104229610
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
251 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


The activation energies for reaction of phenylchloro carbene with pyridine, tri-nbutyl-tin hydride and triethylsilane are reported. The data argues against reversibly formed complexes in the reaction of this carbene with olefins.