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Activation parameters for hindered rotation in N′-t-butyl-N,N-dimethylformamidine

✍ Scribed by David L. Harris; Keith M. Wellman

Book ID
104223017
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
192 KB
Volume
9
Category
Article
ISSN
0040-4039

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✦ Synopsis

We wish to report the first successful measurement of the activation parameters for hindered rotation about the C-N bond in a triallcylated m\N-Me(B)

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Hindered rotation about the carbon-nitro
Hindered rotation about the carbon-nitrogen single in N′-aryl-N,N-dimethylformamidines
✍ Domenick J. Bertelli; J.T. Gerig 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 195 KB

which deserves further cownent. Examination of the data presented by the authors o; the above-mentioned communication indicates that the a have failed to differentiate between two unrelated pheonomena which led them to misleading conclusions. This fact can best be demonstrated by data of our own wh