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Activation of tertiary paraffins by elemental fluorine

โœ Scribed by Chava Gal; Shlomo Rozen


Book ID
104229999
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
214 KB
Volume
25
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Elemental fluroine was found to substitute, in a regio and stereospecific way, tertiary unactivated hydrogens in alkanes -the most unreactive family of organic compounds.


๐Ÿ“œ SIMILAR VOLUMES


Selective activation of organic molecule
โœ Shlomo Rozen; Chava Gal ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 59 KB

Reactions on tertiary hydrogen atoms, attached to unactivated saturated carbons, are very rare and usually inefficient. The electron density however, of a carbon-tertiary hydrogen bond is relatively