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Activation of Inert C—H Bonds

✍ Scribed by Fumitoshi Kakiuchi; Naoto Chatani


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Enhanced Activity and Selectivity in Cyc
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## Abstract Herein, we demonstrate that the chain‐initiating dissociation of cyclohexyl hydroperoxide, CyOOH, is substantially accelerated by H‐bond acceptors (e.g. Teflon), which assist OO bond breaking by stabilising the leaving ^⋅^OH radical. This is a completely new approach to boost the chain