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Activation of Hydrogen on Iridium(I) Centers in Water: Solvent Effects, pH Effects, and Iridium−Hydride Exchange with D 2 O

✍ Scribed by Paterniti, David P.; Roman, Paul J.; Atwood, Jim D.

Book ID
125999895
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
229 KB
Volume
16
Category
Article
ISSN
0276-7333

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The effect of iridium dispersion on the activity of Ir/SiO 2 for the selective reduction of NO with CO in the presence of O 2 and SO 2 has been investigated. The intrinsic activity, expressed in terms of turnover frequency (TOF), increases with decreasing iridium dispersion, indicating that NO reduc