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Activation of carbon dioxide by electron transfer and transition metals. Mechanism of nickel-catalyzed electrocarboxylation of aromatic halides

✍ Scribed by Amatore, Christian; Jutand, Anny

Book ID
126023792
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
849 KB
Volume
113
Category
Article
ISSN
0002-7863

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The electrochemical reduction of aryl and vinyl triflates in presence of an electron source, so that they react with electrophiles such as CO 2 . The reaction proceeds through an the presence of CO 2 and a catalytic amount of palladium results in the formation of aromatic and Ξ±,Ξ²-unsaturated activat