Activation of Carbon Dioxide by Coordination with Cations in the Gas Phase: SiF-Mediated Coupling of CO2 and Aromatic CH Bonds

✍ Scribed by Dr. Patrizio Cecchi; Dr. Maria Elisa Crestoni; Prof. Felice Grandinetti; Dr. Vittorio Vinciguerra

• Publisher: John Wiley and Sons
• Year: 1996
• Tongue: English
• Weight: 381 KB
• Volume: 35
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.199625221

✦ Synopsis

COMMUNICATIONS 0.90 -0.80 -0.70 -0.60 -940.8

(3) A' , z = I , p =1.630 gcm-'. p = 2.032 mm-', crystal size 0.20 x 0.20 x 0.40 mm, F(000) = 480.0; 5531 unique reflections and 5468 assumed as observed with 1>2u(l). 268 parameters, R(F,) = 0.0461. R,IF,I* = 0.1025 and S = 0.966. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge CryStdllOgrdphic Data Centre as supplementary publication no. CCDC-179-97. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ. UK (fax: Int. code + (I 223) 336-033, e-mail: teched(a'chemcrys.cam.ac.uk).