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Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid

✍ Scribed by Baglia, Regina A.; Dürr, Maximilian; Ivanović-Burmazović, Ivana; Goldberg, David P.

Book ID
121875252
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
387 KB
Volume
53
Category
Article
ISSN
0020-1669

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We find an unusual example in which different clusters can be isolated from the same reaction mixture depending on the choice of counter-ion. The complex [(bipy),Mn(III)(~-O),Mn(IV)(bipy),]3+ (1 is isolated from Mn(II) and permanganate in acetate buffer with C104-, but [(blpy)(H,O)Mn(III)(~-O)(p-