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Activation-controlled outer-sphere oxidation of thiosulfate: reaction with bis(1,4,7-triazacyclononane)nickel(III)

✍ Scribed by Sarala, Rajeshuni; Stanbury, David M.

Book ID: 120634271
Publisher: American Chemical Society
Year: 1992
Tongue: English
Weight: 950 KB
Volume: 31
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00039a021

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## Abstract A comparative kinetic study of the reactions of two mixed valence manganese(III,IV) complexes of macrocyclic ligands, [L^1^Mn^IV^(O)~2~Mn^III^L^1^], **1** (L^1^ = 1,4,8,11‐tetraazacyclotetradecane) and [L^2^Mn^IV^(O)~2~Mn^III^L^2^], **2** (L^2^ = 1,4,7,10‐tetraazacyclododecane) with thi