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Activation and deactivation of cobalt catalysts in the hydrogenation of carbon dioxide

✍ Scribed by G. Fröhlich; U. Kestel; J. Łojewska; T. Łojewski; G. Meyer; M. Voß; D. Borgmann; R. Dziembaj; G. Wedler


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
954 KB
Volume
134
Category
Article
ISSN
0926-860X

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Activation and Deactivation of Cp*Ir(TsD
✍ Christopher S. Letko; Zachariah M. Heiden; Thomas B. Rauchfuss 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 180 KB

## Abstract The addition of H~3~PO~4~ to Cp\*Ir(TsDPEN‐H), where TsDPEN = H~2~NCHPhCHPhNTs^–^, is a simple method to obtain a water‐soluble hydrogenation catalyst capable of reducing aromatic ketones to their corresponding alcohols in aqueous solutions. Key to the reactivity is the low affinity of