✦ LIBER ✦
Action du cyanure mercurique sur quelques halogénures de désoxy-3-trifluoroacétamido-3-D-ribofurannosyle. Note de laboratoire
✍ Scribed by par Jean M. J. Tronchet; Annie Grouiller; Olivier R. Martin
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- German
- Weight
- 431 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Reactions of Some 3‐Deoxy‐3‐trifluoroacetamido‐D‐ribofuranosyl Halides with Mercuric Cyanide
The expected 2,5‐anhydro‐D‐allononitrile 11 was obtained when the 2‐O‐benzoyl‐3‐deoxy‐3‐trifluoroacetamido‐D‐ribofuranosyl bromide reacted with mercuric cyanide, whereas the isomeric 1,2‐O (1‐cyanoethylidene) derivative was formed from the 2‐O‐acetylated halide; no reaction occurred when the halide was 2‐O‐p‐nitrobenzoylated.