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Action d'agents nucleophiles sur les 4-arylideneisoxazoline-5-ones, synthese et etude de la stereoisomerie de 4-cinnamylideneisoxazoline-5-ones.

✍ Scribed by A. Maquestiau; Y. Van Haverbeke; R.N. Muller; G. Lo Vecchio; G. Grassi


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
134 KB
Volume
14
Category
Article
ISSN
0040-4039

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✍ André Giddey; Florea G. Cocu; Béatrice Pochelon; Théodore Posternak 📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 German ⚖ 879 KB

## Abstract On treatment with diazomethane, 2,4,6/3,5‐penta‐acetoxy‐cyclohexanone(penta‐O‐acetyl‐__myo__‐inosose‐2 or ‐__scyllo__‐inosose) gave only a spiroepoxide. In contrast, replacement of diazomethane by higher diazoalkanes furnished a mixture of alkylspiroepoxides and of ring expansion produc