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Acrylamide polymerization kinetics in gel electrophoresis capillaries. A Raman microprobe study

✍ Scribed by Rapp, Tracey L.; Kowalchyk, Will K.; Davis, Kevin L.; Todd, Elizabeth A.; Liu, Kei Lee; Morris, Michael D.


Book ID
127236369
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
524 KB
Volume
64
Category
Article
ISSN
0003-2700

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Acrylamide was polymerized in acetonitrile at 82 Β°C with a perfluorinated azo-derivative initiator. The polymerization proceeded heterogeneously. Varying amounts of initiator and monomer were used. The activation energy was deduced from three experiments carried out at 59, 71, and 82 Β°C. The followi