Acrylamide Homopolymers and Acrylamide– N -Isopropylacrylamide Block Copolymers by Atomic Transfer Radical Polymerization in Water
✍ Scribed by Wever, D. A. Z.; Raffa, P.; Picchioni, F.; Broekhuis, A. A.
- Book ID
- 118733803
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 815 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0024-9297
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Polyacrylamide was grafted from N-chlorosulfonamide groups onto crosslinked polystyrene beads using copper-mediated atom transfer radical polymerization (ATRP) methodology. A beaded polymer with a polyacrylamide surface shell was prepared in four steps, starting from styrene-divinylbenzene (10%) cop
## Abstract __N__‐Hydroxyethylacrylamide (HEAA) was polymerized using the atom transfer radical polymerization (ATRP) with ethyl 2‐chloropropionate (ECP), copper(I) chloride (CuCl), and tris[2‐(dimethylamino)ethyl]amine (Me~6~TREN) in ethanol/water, producing poly(__N__‐hydroxyethylacrylamide) (PHE