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Acoustical parameters of poly(vinyl pyrrolidone) in N,N-dimethyl formamide solutions

✍ Scribed by K. Chowdoji Rao; S. Venkata Naidu; A. Varada Rajulu


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
173 KB
Volume
26
Category
Article
ISSN
0014-3057

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✦ Synopsis


Ultrasonic velocity, viscosity, density and refractive index measurements have been made for solutions for poly(vinyl pyrrolidone) (PVP; viscosity average molecular weight --40,000) in N,N-dimethyl formamide (DMF) at various concentrations and temperatures. The molar compressibility (ill specific acoustic impedance (Z), Rao number (R), Van der Waals constant (b) and the relaxation strength (r) have been computed. The variations of fl, Z, R and b with concentration at several temperatures have been studied; the solute-solvent interaction for PVP in DMF is confirmed.


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The aqueous solution properties of poly ( N-vinyl-2-pyrrolidone ) ( PVP )denaturing agents ( i.e., thiourea, guanidinium chloride, and carbonate ) were studied by viscosity measurements. The polymer dimensions were calculated at 25ЊC and at previously determined theta temperatures. The unperturbed d