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Acidity of Hydrocarbons. XIX. Kinetics and Mechanism of Exchange of Benzene and sec-Butylbenzene with Cesium Cyclohexylamide 1

โœ Scribed by Streitwieser, A.; Caldwell, R. A.


Book ID
126154221
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
760 KB
Volume
87
Category
Article
ISSN
0002-7863

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Acidity of Hydrocarbons. XLI. Kinetic ac
โœ A. Streitwieser Jr.; M.J. Maskornick; G.R. Ziegler ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

We have shown recently (1) that the kinetic acidity of the bridgehead position of triptycene, I, can be quantitatively accounted for on the basis of the s-character in the C-H bond as measured by J13C\_H, and by the inductive field effect of the aryl carbons as measured by Cl/r. The success of the C