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Acidity and basicity of azoles: Solvent effects

✍ Scribed by J. Catalan; M. Sanchez-Cabezudo; J.L.G. de Paz; J. Elguero


Book ID
119117222
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
169 KB
Volume
166
Category
Article
ISSN
0166-1280

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The diiodine basicity (a soft Lewis basicity) of 15 azoles (imidazoles, pyrazoles and triazoles) was measured by means of the formation constant of the diiodine-azole complexes in heptane at 298 K. The preferred sites of diiodine fixation are the nitrogens N-3 in imidazoles, N-2 in pyrazoles and N-4