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Acid/Base-controlled supramolecular switch

โœ Scribed by Matthews, Owen A.; Raymo, Francisco M.; Fraser Stoddart, J.; White, Andrew J. P.; Williams, David J.

Book ID
120772640
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
129 KB
Volume
22
Category
Article
ISSN
1144-0546

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Our studies allowed to unravel at least partially, the "so-called" spontaneous self-assembly processes of supramolecular edifices based on metals. The formation of a tricuprous double-stranded helix in solution was found to be driven by thermodynamics via highly distorted intermediates. Dinuclear eu