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Acid Reversion Products from D-Glucose

โœ Scribed by Thompson, A.; Anno, Kimiko; Wolfrom, M. L.; Inatome, M.


Book ID
111966416
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
453 KB
Volume
76
Category
Article
ISSN
0002-7863

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Reaction of a 4: 1 mixture of D-ribono-and D-arabinono-I ,4-lactones with benzaldehyde and hydrochloric acid gave 59% crystalline 3,4-O-benzyhdene-D-ribono-1,5-lactone. This acetal was oxidized with manganese dioxide in acetone to its 2-keto derivative (6) in 76% yield. Acid-catalyzed methanolysis