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Acid-catalyzed solvolyses of bicyclobutane derivatives. Stereochemistry of the cyclopropylcarbinyl-cyclopropylcarbinyl and related rearrangements

✍ Scribed by Wiberg, Kenneth B.; Szeimies, Guenter.


Book ID
126275111
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
1019 KB
Volume
92
Category
Article
ISSN
0002-7863

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## Abstract The buffered trifluoroethanolyses and acetolyses of __exo__‐(2‐D)‐ **(6)** and __endo__‐(2‐D)‐5‐norbornen‐2‐yl brosylates **(7)** yielded __exo__‐5‐norbornen‐2‐yl and 3‐nortricyclyl derivatives. The deuterium distribution in these products was determined unambiguously by ^2^H‐NMR. and M