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Acid-Catalyzed Rearrangements of Some Bicyclic δ-Hydroxy-α,β-enones

✍ Scribed by Swaminathan, S.; Natarajan, R. K.; Ramachandran, S.; Sankarappa, S. K.


Book ID
126325742
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
347 KB
Volume
31
Category
Article
ISSN
0022-3263

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On the mechanism of the base catalysed r
✍ S. Chandrasekaran; P.S. Venkataramani; K.G. Srinivasen; S. Swaminathan 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 250 KB

Bicyclic-b-hydroxy-WIP -enone (1) to (4) have been shown to rearrange in the presence or bases, acid8 and also photochemically. 2,3,4,5, The medlanism that haa been suggested for the base catalysed reaction ia illU8trated with the fl) R=-C&CH (2) R= -CH=CH2 (3) ## R= -Me (4) R= -H A Cope-type me