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Acid-catalyzed reaction of 3-methylbut-3-ene-1-ol with formaldehyde

✍ Scribed by V. I. Heifets; V. Z. Sharf; G. K. Oparina; M. K. Bychkova; V. P. Babukh; L. Kh. Freidlin


Book ID
112434937
Publisher
Springer
Year
1968
Tongue
English
Weight
187 KB
Volume
17
Category
Article
ISSN
1573-9171

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## Abstract The title cyclohexenone **1d** undergoes photodimerization selectively at the exocyclic CC bond to give a 1 : 1 mixture of 1,2‐dialkynyl‐1,2‐dimethylcyclobutanes **6** and **7**. On irradiation in the presence of 2,3‐dimethylbuta‐1,3‐diene, **1d** affords bicyclo[8.4.0]tetradeca‐1,2,3,