Acid-catalyzed oxidation of benzaldehydes to phenols by hydrogen peroxide
β Scribed by Matsumoto, Masakatsu; Kobayashi, Kisako; Hotta, Yasushi
- Book ID
- 111900201
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 276 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The hydroxylation of a series of aromatic hydrocarbons with hydrogen peroxide, catalyzed by iron complexes with pyrazine-3-carboxylic acid N-oxide, was investigated, operating in a biphasic reaction medium. The new catalyst showed a high selectivity to the corresponding phenols, minimizing the over
## 4-t-Butyltoluene can be oxidised in acetic acid to 4-r-butylbenzaldehyde by hydrogen peroxide in a process catalyzed by cerium(II1) and bromide ions. The conversion proceeds via benzylic bromination, hydrolysis of the bromide to alcohol and the rapid oxidation of the alcohol to the aldehyde by