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Acid-catalyzed decomposition of 1-aryl-1-methylethyl benzenethiosulfinates. A search for neighboring-group participation in acid-catalyzed decomposition of thiosulfinates

โœ Scribed by Faehl, Larry G.; Kice, John L.


Book ID
120657787
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
427 KB
Volume
45
Category
Article
ISSN
0022-3263

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An qJ?cient method has been developed for the stereoselective substitution of ## 7-oxabicyclo[2.2.l]hept-2-yl derivatives by protected amino group at C(S-exo) and hydroxy group at C(6-endo). The 7-oxabicyclo[2.2.1]hept-S-en-2-yl derivatives 1 -6 can be obtained optically pure.' Because of their b