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Acid-Catalyzed Amide Hydrolysis Assisted by a Neighboring Amide Group

โœ Scribed by Cohen, Theodore.; Lipowitz, Jonathan.

Book ID
127286264
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
842 KB
Volume
86
Category
Article
ISSN
0002-7863

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Unusual ammonolysis of a secondary amide
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โœ Antonio Arcelli; Gianni Porzi; Sergio Sandri ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 400 KB

Evidence for the participation of neighboring -CONH 2 group in the ammonolysis of disubstituted amide was obtained. The surprising conversion of I into 3 in very. mild conditions is a process formed by two consecutive first order reactions. Kinetics were performed in ethanol at various temperatures