Acid catalyzed aldol condensation in the gas phase
β Scribed by Chrysostomos Wesdemiotis; Fred W. McLafferty
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 175 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Burinsky and Cooks' have reported that deprotonated dimethyl adipate eliminates methanol via a gas-phase Dieckmann condensation. This is in contrast to the behaviour of simple methyl ester enolates which lose MeOH by a different mechanism, e.g. MeOCOCHCH,R + [M&(OCCHCH,R)] + O-C-CHCHR + MeOH. Eviden
## Dedicated to the memory of Prof. Giacomino Randazzo The factors responsible for the diastereoselective formation of the 6-endo-hydroxybicyclo[2.2.2]octan-2one by acid-catalyzed intramolecular aldol reaction of 3-oxocyclohexaneacetaldehydes have been investigated. This study, carried out on (1SR