Acid-base reactions of tungsten and uranium oxide fluorides in anhydrous hydrogen fluoride
โ Scribed by Yasushi Katayama; Rika Hagiwara; Yasuhiko Ito
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 659 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0022-1139
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๐ SIMILAR VOLUMES
When group VI elements and uranium were reacted with chlorine-hydrogen fluoride mixtures, good yields of WF6 were found in the case of W, while only MoF5, MO" chlorofluorides, and a spectroscopic trace of MoF6 were found when the element was MO. Uranium gives UFq at lower temperatures whereas at hi
Simple protonic superacid anhydrous hydrogen fluoride (aHF) and its use as solvent in reactions with high-oxidation-state materials is described. A general scheme for an acid-base dependence of the formation of fluorocations, binary compounds or fluoroanions is exemplified by the syntheses of comple