Acid-base characteristics of functionally 4-substituted 4-alkyl-7-aminocoumarins
✍ Scribed by M. A. KirpichËnok; L. A. Karandashova; I. I. Grandberg
- Publisher
- Springer US
- Year
- 1991
- Tongue
- English
- Weight
- 465 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0009-3122
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract ω‐Azolylacetophenones **1** and **2** react with dimethylformamide dimethylacetal to yield enaminones **7,8** that were converted into azolylazoles __via__ reaction with hydrazine and with hydroxylamine. Compounds **1,2** also coupled with aromatic diazonium salts to yield arylhydrazone
The absorption and luminescence spectra of a series of 4,7-diaminocoumarins have been investigated in ethanol and acetonitrile solution. The pkJ and pkJ 1 values for several of the compounds have been measured. It has been found that the site of primary protonation is the nitrogen atom in the 7-posi