## Abstract In this paper, we report two metal–organic frameworks [Co~3~(ndc)~3~(bipyen)~1.5~]⋅H~2~O (1) and [Co~2~(ndc)~2~(bipyen)]⋅C~6~H~6~⋅H~2~O (2) (bipyen=__trans__‐1,2‐bis(4‐pyridyl)ethylene, H~2~ndc=2,6‐naphthalenedicarboxylic acid). These compounds were both synthesized from identical hydro
✦ LIBER ✦
Acid-assisted hydrothermal synthesis and adsorption properties of high-specific-surface metal–organic frameworks
✍ Scribed by Ma, Yuanhui; Lin, Jing; Xue, Yanming; Li, Jie; Huang, Yang; Tang, Chengchun
- Book ID
- 124086272
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 804 KB
- Volume
- 132
- Category
- Article
- ISSN
- 0167-577X
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A new metal-organic framework [Fe 3 O(OOC-C 6 H 4 -COO) 3 (H 2 O) 3 ]Cl$(H 2 O) x was synthesized with a specific surface area of 2823 m 2 /g and a lattice parameter of 88.61 A ˚. Isostructural with MIL-101, this compound exhibits similar hydrogen adsorption properties, with maximum adsorption capac