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Achiral Dihydroxylation of Olefins by Osmate (OsO42−) Stabilised on Nanocrystalline Magnesium Oxide

✍ Scribed by Boyapati M. Choudary; Karangula Jyothi; Mannepalli L. Kantam; B. Sreedhar

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
93 KB
Volume
346
Category
Article
ISSN
1615-4150

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Asymmetric Epoxidation of Olefins by Man
Asymmetric Epoxidation of Olefins by Manganese(III) Complexes Stabilised on Nanocrystalline Magnesium Oxide
✍ B. M. Choudary; Ujjwal Pal; M. Lakshmi Kantam; K. V. S. Ranganath; B. Sreedhar 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 179 KB

## Abstract The asymmetric epoxidation of unfunctionalised olefins to epoxides is realised by using manganese(III) complexes stabilised on nanocrystalline magnesium oxide in the presence (1__R__,2__R__)‐(−)‐diaminocyclohexane as a chiral ligand in good yields and up to 91 % enantiomeric excess.