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“Achiral” Benzophenone Ligand for Highly Enantioselective Ru Catalysts in Ketone Hydrogenation.

✍ Scribed by Koichi Mikami; Kazuki Wakabayashi; Kohsuke Aikawa


Publisher
John Wiley and Sons
Year
2006
Weight
16 KB
Volume
37
Category
Article
ISSN
0931-7597

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Solution Structure and Behavior of Benzo
✍ Qing Jing; Christian A. Sandoval; Yoshiki Yamaguchi; Koichi Kato; Kui-Ling Ding 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB

## Abstract We herein report on solution structural studies of Ru^II^ catalysts (**3a**, **9**) composed of achiral bisphosphine ligands (**4**, **8**) and the enantiopure 1,2‐diphenylethylenediamine (DPEN). Complete chiral induction from enantiopure (__R__,__R__)‐DPEN to achiral bisphosphine ligan