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Acetylenes Rearranging on Ruthenium–Porphyrinogen and Leading to Vinylidene and Carbene Functionalities

✍ Scribed by Lucia Bonomo; Christine Stern; Euro Solari; Rosario Scopelliti; Carlo Floriani


Book ID
101367228
Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
116 KB
Volume
113
Category
Article
ISSN
0044-8249

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UV Irradiation of 3-oxocyclopent-1-enyl acetate (17) and acetylene in MeCN at 0" gives, besides the product of normal enone-alkyne [2 + 21 cycloaddition (cis-4-oxobicyclo[3.2.0]hept-6-en-l-yl acetate, 18) and its product of oxd-di-n methane rearrangement (5-oxotricyclo[4.1 .0.02.']hept-2-yl acetate,