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Acetylene Chemistry (Chemistry, Biology, and Material Science) || Acetylenosaccharides

✍ Scribed by Diederich, François; Stang, Peter J.; Tykwinski, Rik R.

Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
Year
2005
Tongue
German
Weight
536 KB
Edition
1
Category
Article
ISBN
3527307818

No coin nor oath required. For personal study only.

✦ Synopsis

Scheme 5.2 Polyacetylenes isolated from Basilidiomycete (7-13), Hyphomycete (14), and Actinomycete (15). O AcO AcO NAc OAc OAc O=N OAc AcO OAc O O Ph OAc AcO CO 2 Me N 2 O O Ph OAc 24 26 1) KOH, i PrOH/Et 2 O, -25°2 ) Ac 2 O, py 25 (70%) 27 (30%) Scheme 5.6 Degradation of the nitrosoacetamide 24 and the diazo ester 26.

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