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Acetoxytropyliumbromid: Synthese, Strukturbeweis, Verhalten in Lösung

✍ Scribed by Peter Engel; Urs Martin Keller; Peter Bigler; Markus Neuenschwander

Publisher
John Wiley and Sons
Year
1976
Tongue
German
Weight
597 KB
Volume
59
Category
Article
ISSN
0018-019X

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✦ Synopsis

Acetoxytropyliumbromide: Synthesis, Structural Evidence, Behaviour in Solution.

Acetoxytropyliumbromide (9) is formed from tropone and acetylbromide. In solution the tropylium salt equilibrates with the educts, 9 being favored at low temperature in polar aprotic solvents. The structure of the title compound has been proved by X‐ray analysis, as well as by investigation of the ^1^H‐NMR. spectra of solutions of 9.

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