Acetoxylation of β-lactams with lead(IV) Acetate
✍ Scribed by Le Thanh Giang; József Fetter; Mária Kajtár-Peredy; Károly Lempert; Gábor Czira
- Book ID
- 104209707
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 541 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
I-(4-Methoxyphenyl)azetidin-2-ones Sa-5g were acetoxylated by lead(IV) acetate to afford the corresponding compounds 6a. 6b. 6c' and 6d-6g. In the d series elimination products 9 <and ltl were also formed. Ring homologue 7a afforded the hydrosylated derivative 8'a.
📜 SIMILAR VOLUMES
## PhI(OAc), is an effective oxidant in the acetoxylation of arenes with Pd(OAc), as catalyst. The data are most easily interpreted in terms of palladation bein g the step that determine.4 both the rate and the O/IN/~J selectivity, and reductive elimination from a PhPdW(OAcI species being the prod