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Acetoxylation of β-lactams with lead(IV) Acetate

✍ Scribed by Le Thanh Giang; József Fetter; Mária Kajtár-Peredy; Károly Lempert; Gábor Czira


Book ID
104209707
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
541 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis


I-(4-Methoxyphenyl)azetidin-2-ones Sa-5g were acetoxylated by lead(IV) acetate to afford the corresponding compounds 6a. 6b. 6c' and 6d-6g. In the d series elimination products 9 <and ltl were also formed. Ring homologue 7a afforded the hydrosylated derivative 8'a.


📜 SIMILAR VOLUMES


A redetermination of lead(IV) acetate
✍ Schürmann, M. ;Huber, F. 📂 Article 📅 1994 🏛 International Union of Crystallography 🌐 English ⚖ 459 KB
Pd(II) catalyzed acetoxylation of arenes
✍ Takahiro Yoneyama; Robert H. Crabtree 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 600 KB

## PhI(OAc), is an effective oxidant in the acetoxylation of arenes with Pd(OAc), as catalyst. The data are most easily interpreted in terms of palladation bein g the step that determine.4 both the rate and the O/IN/~J selectivity, and reductive elimination from a PhPdW(OAcI species being the prod