## Abstract Mass spectrometrical and ^1^H‐NMR.‐analyses of the __exo__‐5‐norbornen‐2‐yl acetate, formed by acetolysis of __endo__‐5‐norbornen‐2‐yl‐2‐__exo__‐d brosylate, demonstrate that the deuterium initially on C(2) migrates partially (30%) onto C(1) (mechanism Ia or Ib). No deuterium could be d
✦ LIBER ✦
Acetolysis of Δ4-cyclooctenyl carbinyl brosylate and endo 2-bicyclo[3.3.1]Nonyl brosylate
✍ Scribed by Hugh Felkin; Geneviève Le Ny; Claude Lion; W.D.Keith Macrosson; John Martin; William Parker
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 248 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Cationic cyclisations involving double bonds are often concer-:ed processes, and, in suitable systems, the double bond can pro-,ide substantial driving force (1). Hanack and Kaiser (2), in
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