𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Acetolysis of the epimeric 3,3-dimethyl-7-tosyloxybicyclo[2.2.1]heptan-2-ones. Interaction between incipient carbonium ions and neighboring nonenolizable ketones

✍ Scribed by Gassman, Paul G.; Hornback, Joseph M.


Book ID
126447443
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
589 KB
Volume
91
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Acetolysis of the epimeric 3,3-dimethyl-
✍ Paul G. Gassman; Joseph M. Hornback πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 200 KB

Recently we reported that the rate determining step in the unusually rapid solvolysis of anti-7-tosyloxybicyclo[2.2.l]heptan-2-one (I.) was the conversion of 1 into its enol, & The enol then ionized in a fast step to give an intermediate which collapsed to give 2 with complete retention of stereoche