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Acetolysis of 6-carbomethoxy-2-norbornyl brosylates

โœ Scribed by G.W. Oxer; D. Wege

Book ID
104247396
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
201 KB
Volume
12
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The solvolysis of 2-norbornyl derivatives continues to command considerable interest, largely because of the controversy as to whether the 2-norbornyl cation is best formulated as a bridqed,

๐Ÿ“œ SIMILAR VOLUMES

The solvolysis of 5-keto-2-norbornyl bro
The solvolysis of 5-keto-2-norbornyl brosylates
โœ Joe C. Greever; Donald E. Gwynn ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 195 KB

Numerous studies have shown the P-norbornyl cation to exhibit a remarkable degree of exo-stereospecificity upon nucleophilic substitution. 1 2-4 Some recent work, however, has shown this stereospecificity to be lost upon incorporation of an electron withdrawing substituent located either 01 or S to