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Acetolysis of 2-(endo-5-norborgen-2-yl)ethyl p-bromobenzenesulfonate

✍ Scribed by Evan L. Allered; Tom J. Maricich

Book ID
104241942
Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
243 KB
Volume
4
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Nature of the 5-norbornen-2-yl Cation In
Nature of the 5-norbornen-2-yl Cation Intermediate in the acetolysis of 2-deuterio-endo-5-norbornen-2-yl brosylate
✍ Pierre Vogel; Roland Delseth; Daniel Quarroz πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 German βš– 814 KB

## Abstract Mass spectrometrical and ^1^H‐NMR.‐analyses of the __exo__‐5‐norbornen‐2‐yl acetate, formed by acetolysis of __endo__‐5‐norbornen‐2‐yl‐2‐__exo__‐d brosylate, demonstrate that the deuterium initially on C(2) migrates partially (30%) onto C(1) (mechanism Ia or Ib). No deuterium could be d

The solvolyses of exo- and endo-5-norbor
The solvolyses of exo- and endo-5-norbornen-2-yl p-bromobenzenesulfonates. A re-investigation using deuterium nmr spectroscopy.
✍ Jean-Marie Sonney; Pierre Vogel; Ulrich Burger πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 188 KB

The solvolyses of 5-norbornen-2-yl esters have posed a considerable problem in interpretation, especially since there are divergences between the reported results. 1,2,3 Recently, It has been suggested on the basis of a tritium labeling study that the process involves a pair of enantiomeric homoall