๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Acetoacetylation with 2,2,6-trimethyl-4H-1,3-dioxin-4-one: a convenient alternative to diketene

โœ Scribed by Clemens, Robert J.; Hyatt, John A.


Book ID
111692275
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
639 KB
Volume
50
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Reaction of 2,2,6-T
โœ A. D'ANNIBALE; A. PESCE; S. RESTA; C. TROGOLO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 1 views

Reaction of 2,2,6-Trimethyl-4H-1,3-dioxin-4-one with Imines: An Easy Route to Enamides. -Thermolysis of the dioxin (I) generates an acylketene which is readily trapped by imines to give the N-alkenyl acetoacetamides (III). They are useful intermediates in oxidative radical cyclizations leading to .