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Acetoacetoxy ethyl methacrylate (AAEM) resin, a new scavenger for primary amines in the presence of secondary amines

✍ Scribed by Zhanru Yu; Sonia Alesso; David Pears*; Paul A Worthington; Richard W.A Luke; Mark Bradley


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
81 KB
Volume
41
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Acetoacetoxy Ethyl
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Effects of mixed H2OCH3CN solvents on th
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Nucleophilic second-order rate constants, k n ms , for the reactions of several primary and secondary amines with ionized phenyl salicylate (PS Οͺ ) show a nonlinear decrease with the increase in the content of CH 3 CN from 2 to Υ…50% v/v in mixed aqueous solvent. The values of k n ms remain almost un