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Acetic acid—water system thermodynamical correlation of vapor—liquid equilibrium data

✍ Scribed by E. Sebastiani; L. Lacquaniti

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
671 KB
Volume
22
Category
Article
ISSN
0009-2509

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✦ Synopsis

A considerable amount of data for vapor-liquid equilibrium between acetic acid and water are compared with a set of experimental results, obtained by means of a modified Gillespie still at atmospheric pressure.

Using the differential heats of mixing, all the actlvlty coefficients were reported to 25°C; in this manner it was possible to compare also the data related to pressures different from atmospheric.

By means of Redlich and Kister equations, a thermodynamical correlation for the activity coefficients as functions of the temperature and composition was obtained.

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