Acetate-catalyzed enolization of 2-butanone
β Scribed by Warkentin, John; Cox, Robin A.
- Book ID
- 125898244
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 433 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract The acidβcatalyzed enolization of acetone in the presence of bromine is found to be catalyzed by the anionic micelles of sodium dodecyl sulfate. The rate acceleration expected on the basis of lowering of activation energy is largely nullified by the decrease in the entropy of activation
## Summarv: Irradiation of benzene solutions containing a cyanoarene sensitizer, 1,3-cyclohexadiene, and a trimethylsilyl enol ether or ketene acetal leads to intermolecular [4+2] and [2+2] cycloaddition products. The Diels-Alder reaction is widely regarded as among the most useful and general of