Accurate quartic and sextic centrifugal distortion constants of

✍ Scribed by L. Bizzocchi; L. Cludi; C. Degli Esposti

• Book ID: 104151742
• Publisher: Elsevier Science
• Year: 2003
• Tongue: English
• Weight: 122 KB
• Volume: 218
• Category: Article
• ISSN: 0022-2852
• DOI: 10.1016/s0022-2852(02)00080-2

✦ Synopsis

1-Phosphapropyne has been produced in the gas phase by pyrolysis of a mixture of ethane and phosphorus trichloride. The ground state rotational spectra of the most abundant isotopomer and of the isotopic variants 13 CH 3 CP and CH 3 13 CP have been investigated in the millimeter and submillimeter wave regions obtaining very accurate values of the quartic centrifugal distortion constants D J and D JK and of the sextic distortion constants H JK and H KJ .