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Accurate Prediction of Band Gaps in Neutral Heterocyclic Conjugated Polymers

✍ Scribed by Hutchison, Geoffrey R.; Ratner, Mark A.; Marks, Tobin J.

Book ID
120519209
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
289 KB
Volume
106
Category
Article
ISSN
1089-5639

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## Abstract **Summary:** A novel narrow‐band‐gap conjugated polymer with heterocyclic backbone, poly[4,7‐bis(4‐decanyl‐2‐thienyl)‐2β€²,1β€²,3^β€²^‐benzothiadiazole‐thiophene‐2,5‐] (PDDBT, __E__~g~ = 1.38 eV) was synthesized by a Stille coupling reaction. Prototype bulk heterojunction photovoltaic cells f