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Accurate numerical orbital MBPT/CC study of the electron affinity of fluorine and the dissociation energy of hydrogen fluoride

✍ Scribed by Adamowicz, Ludwik; Bartlett, Rodney J.


Book ID
125861413
Publisher
American Institute of Physics
Year
1986
Tongue
English
Weight
427 KB
Volume
84
Category
Article
ISSN
0021-9606

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The kinetics of the thermal elimination of H F from 1,2-difluoroethane CHzFCHzF -+ CHz=CHF + H F have been studied in a static system over the temperature range 734-820'K. was shown to be first order and homogeneous, with a rate constant of The reaction log kz(s-l) = 13.39 f 0.2 -(62.9 f 0.9)/0 wher